MgH<sub>2</sub>@Mg(BH<sub>4</sub>)<sub>2</sub> Core–Shell-like Nanostructures: Synthesis, Hydrolysis Performance, and Promotion Mechanism
Yongyang Zhu, Liming Zeng, Daifeng Wu, Shun Wang, Qing Zhou, Renheng Tang, Gary Chi-Pong Tsui, Zheng‐Long Xu, Xusheng Yang, K.C. Chan
Abstract
The hydrolysis of hydrides, represented by MgH 2, delivers substantial capacity and presents an appealing prospect for an on-site hydrogen supply. However, the sluggish hydrolysis kinetics and low hydrogen yield of MgH 2 caused by the formation of a passivation Mg(OH) 2 layer hinder its practical application. Herein, we present a dual strategy encompassing microstructural design and compounding, leading to the successful synthesis of a core–shell-like nanostructured MgH 2 @Mg(BH 4 ) 2 composite, which demonstrates excellent hydrolysis performance. Specifically, the optimal composite with a low E a of 9.05 kJ mol –1 releases 2027.7 mL g –1 H 2 in 60 min, and its hydrolysis rate escalates to 1356.7 mL g –1 min –1 H 2 during the first minute at room temperature. The nanocoating Mg(BH 4 ) 2 plays a key role in enhancing the hydrolysis kinetics through the release of heat and the formation of local concentration of Mg 2+ field after its hydrolysis. This work offers an innovative concept for the design of hydrolysis materials.