A Family of Heterobimetallic Cubes Shows Spin‐Crossover Behaviour Near Room Temperature
Matthias Hardy, Jacopo Tessarolo, Julian J. Holstein, Niklas Struch, Norbert Wagner, Ralf Weisbarth, Marianne Engeser, Johannes Beck, Shinnosuke Horiuchi, Guido H. Clever, Arne Lützen
Abstract
Abstract Using 4‐(4′‐pyridyl)aniline as a simple organic building block in combination with three different aldehyde components together with metal(II) salts gave three different Fe 8 Pt 6 ‐cubes and their corresponding Zn 8 Pt 6 analogues by employing the subcomponent self‐assembly approach. Whereas the use of zinc(II) salts gave rise to diamagnetic cages, iron(II) salts yielded metallosupramolecular cages that show spin‐crossover behaviour in solution. The spin‐transition temperature T 1/2 depends on the incorporated aldehyde component, giving a construction kit for the deliberate synthesis of spin‐crossover compounds with tailored transition properties. Incorporation of 4‐thiazolecarbaldehyde or N ‐methyl‐2‐imidazole‐carbaldehyde yielded cages that undergo spin‐crossover around room temperature whereas the cage obtained using 1 H ‐4‐imidazolecarbaldehyde shows a spin‐transition at low temperatures. Three new structures were characterized by synchrotron X‐ray diffraction and all structures were characterized by mass spectrometry, NMR and UV/Vis spectroscopy.