Stannylene cyanide and its use as a cyanosilylation catalyst
Vivek Kumar Singh, Prakash Chandra Joshi, Hemant Kumar, Rahul Kumar Siwatch, Chandan Kumar Jha, Selvarajan Nagendran
Abstract
)] (4) using an excess of trimethylsilyl cyanide (L = aminotroponiminate (ATI)). Using 0.1-2.0 mol% of compound 5, catalytic cyanosilylation of a variety of aliphatic and aromatic aldehydes was achieved at rt-50 °C in 0.33-2.0 h. The mechanism of this catalytic reaction is authenticated by the isolation of a structurally characterized intermediate.
Topics & Concepts
CyanideCatalysisTrimethylsilyl cyanideChemistryOrganic chemistrySynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and OrganometallicsOrganoboron and organosilicon chemistry