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Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications

Bhupendra Pratap Singh, Samiksha Sikarwar, Shikha Agarwal, Dharmendra Pratap Singh, Kamal Kumar Pandey, Rajiv Manohar

2023ACS Omega15 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as aggregation-induced emission (AIE) electroluminescent composite systems composed of a nematic liquid crystals (NLC) blended with polyethylene-functionalized gold nanospheres (GNSs). The major findings of this study include superior electro-optical properties such as threshold voltage reduction by around 24%. The fall time is reduced by 11.50, 30.33, 49.33, and 63.17% respectively, and rotational viscosity is reduced by 13.86, 32.77, 36.97, and 49.58% for 5.0 × 10 11, 5.0 × 10 12, 2.5 × 10 13, and 5.0 × 10 13 number of GNS-blended liquid crystal (LC) cells. The increased UV absorbance and greatly enhanced luminescence properties have been attributed to surface plasmon resonance near the surface of GNSs and AIE effect risen due to agglomeration of the capping agent with the NLC molecules respectively, and these characteristics make them suitable for new-age display applications.

Topics & Concepts

Liquid crystalMaterials scienceLuminescenceSurface plasmon resonanceOptoelectronicsAbsorbanceElectroluminescenceNanotechnologyChemical engineeringOpticsLayer (electronics)NanoparticleEngineeringPhysicsLiquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsNonlinear Optical Materials Studies
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