2D covalent organic framework thin films<i>via</i>interfacial self-polycondensation of an A<sub>2</sub>B<sub>2</sub>type monomer
Bowen Zhang, Xiaoyu Song, Yusen Li, Yang Li, Zhongxiang Peng, Long Ye, Long Chen
Abstract
An A2B2 type monomer, 1,6-bis(4-formylphenyl)-3,8-bis(4-aminophenyl)pyrene (BFBAPy), was employed for the fabrication of continuous and highly crystalline 2D imine-linked covalent organic framework (COF) films with tunable thickness via interfacial self-polymerization. These films served as stable acidichromism sensors with rapid response, low detection limit and good repeatability.
Topics & Concepts
MonomerCovalent bondThin filmMaterials scienceCondensation polymerPolymer chemistryPolymerChemical engineeringNanotechnologyChemistryOrganic chemistryComposite materialEngineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials