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Janus Gas Diffusion Layer for Enhanced Water Management in Proton Exchange Membrane Fuel Cells (PEMFCs)

Qinglin Wen, Saifei Pan, Yali Li, Chuang Bai, Min Shen, Hanqing Jin, Fandi Ning, Xuwei Fu, Xiaochun Zhou

2022ACS Energy Letters87 citationsDOI

Abstract

The proton exchange membrane fuel cell (PEMFC) is one of the most promising energy conversion devices. However, a PEMFC is hindered by the serious problem of water management. Herein, a Janus gas diffusion layer (Janus GDL) that can spontaneously transport water from the hydrophobic side to the hydrophilic side was prepared by layer-by-layer filtration and laser drilling. The Janus GDL exhibits a remarkable antiflooding capability at the equivalent current density of 3.25 A cm–2 (2.3–2.5 times compared to the commercial GDL) in the half-cell. Because of the low water breakthrough pressure (29 Pa), the Janus GDL drains excessive water immediately, thus preventing heavy electrode floodings. As a result, the Janus GDL shows a higher peak power density (1.89 W cm–2 vs 1.17 W cm–2 of commercial GDL). Therefore, the Janus GDL is promising for use in PEMFCs and other electrochemical devices to get a good water management.

Topics & Concepts

JanusProton exchange membrane fuel cellWater transportChemical engineeringMembraneDiffusionFuel cellsElectrochemistryPower densityChemistryMaterials scienceElectrodeNanotechnologyEnvironmental engineeringPower (physics)Water flowEnvironmental sciencePhysical chemistryBiochemistryPhysicsQuantum mechanicsThermodynamicsEngineeringFuel Cells and Related MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication
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