Synthesis and characterisation of an iron oxide mesoporous silica nano-composite and its application in removal of methylene blue dye
Wahran M. Saod, Ian W. Oliver, Alessandro Contini, Vladimir L. Zholobenko
Abstract
• Novel composites, FeO nanoparticle loaded mesoporous silica (MCM-41) created. • Material characterization via TGA/TDA, FTIR, XRD, UV–Vis, BET and SEM. • Methylene blue, as example pollutant, adsorption capacity tested and optimised. • Adsorption modelled using Langmuir and Freundlich isotherms. • High capacity for environmental clean-up demonstrated across varying conditions. Globally, effluents from textile industries and other waste streams have the potential to release vast amounts of chemical dyes and related substances into the environment. Treatment of water and waste-water to remove such pollutants is a pressing need and one promising option is the use of matrix-stabilised nanomaterials for pollutant removal via adsorption. Matrix-stabilised nanomaterials are composite substances in which the nanomaterials are embedded in a stable matrix that renders them less susceptible to the flocculation and agglomeration processes that can limit the success of water treatment via conventional nanomaterials. In this study, mesoporous silica (mSiO 2 ) and nano-iron loaded mesoporous silica (FeO-mSiO 2 ) were successfully synthesized and characterised alongside commercially obtained Fe nanoparticles (Fe-NP) using UV–Visible spectral analysis, FTIR, XRD, TGA/TDA and SEM analyses. The surface area of the composite material was typically 29 m 2 /g, with average pore volume 0.042 cm 3 /g, indicating scope for further refining. All test materials were evaluated for their capacity to remove methylene blue, a dye widely used in textile and chemical industries, from water and optimal conditions for removal were determined considering pH, solid: solution ratio, and contact time. Removal by FeO-mSiO 2 equaled or exceeded that of the other substances under most conditions tested, with maximum removal achieved at pH 6–9, contact time 60–120 min, and a sorbent: liquid ratio 1:1000.