1,3,4-Thiadiazole-Containing Azo Dyes: Synthesis, Spectroscopic Properties and Molecular Structure
Agnieszka Kudelko, Monika Olesiejuk, Marcin Łuczyński, Marcin Świa̧tkowski, Tomasz Sierański, R. Kruszyński
Abstract
Three series of azo dyes derived from 2-amino-5-aryl-1,3,4-thiadiazoles and aniline, N,N-dimethylaniline and phenol were synthesized in high yields by a conventional diazotization-coupling sequence. The chemical structures of the prepared compounds were confirmed by 1H-NMR, 13C-NMR, IR, UV-Vis spectroscopy, mass spectrometry and elemental analysis. In addition, the X-ray single crystal structure of a representative azo dye was presented. For explicit determination of the influence of a substituent on radiation absorption in UV-Vis range, time-dependent density functional theory calculations were performed.
Topics & Concepts
AnilineChemistryElemental analysisDimethylanilineSubstituentCarbon-13 NMRProton NMRMass spectrometryAzo couplingPhenolDensity functional theoryArylSpectroscopyChemical structureAbsorption spectroscopySingle crystalPhotochemistryOrganic chemistryComputational chemistryCrystallographyChromatographyAlkylPhysicsQuantum mechanicsDyeing and Modifying Textile FibersSynthesis and biological activitySynthesis and Characterization of Heterocyclic Compounds