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6MNEP: a molecular cation with large hyperpolarizability and promise for nonlinear optical applications

Gabriel A. Valdivia‐Berroeta, Karissa C. Kenney, Erika W. Jackson, Joseph C. Bloxham, Adam X. Wayment, Daniel J. Brock, Stacey J. Smith, Jeremy A. Johnson, David J. Michaelis

2020Journal of Materials Chemistry C28 citationsDOI

Abstract

The featured organic push-pull chromophores 6MNEP-T and 6MNEP-4NBS show from 1.6 to 2.5 times larger calculated macroscopic nonlinearities compared with benchmark organic nonlinear optical crystals.

Topics & Concepts

HyperpolarizabilityMaterials scienceNonlinear opticalNonlinear systemNonlinear opticsNanotechnologyChemical physicsOptoelectronicsQuantum mechanicsPhysicsNonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical StudiesMolecular spectroscopy and chirality
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