Process Design and Techno-ECONOMIC Evaluation of a Decarbonized Cement Production Process Using Carbon Capture and Utilization
Wei Wu, Zhong-Lin Jian, Bang-Yan Chou, Chun-Yang You, Yu-Ning Kuo
Abstract
To address a decarbonized cement production process (DCPP), a calcium looping process is connected to an industrial cement production process (CPP) for capturing CO2 by 93.5~96%. Since the captured CO2 purity is up to 99.9 wt%, the carbon capture and utilization (CCU) process is connected to generate the additional products of urea and methanol. An integration of DCPP and CCU, named the DCPP-based polygeneration system, is being developed for three scenarios. To meet the power demand for producing high-purity hydrogen and oxygen, Scenario 1 adopts water electrolysis and the full green electricity grid; Scenario 2 adopts the Cu-Cl thermochemical cycle and the partial green electricity grid; and Scenario 3 adopts water electrolysis and the heat recovery steam generator (HRSG). Through the techno-economic analysis and comparisons, the CO2 avoided costs of three scenarios are estimated between 16.53 and 21.42 USD/ton, which are lower than the conventional DCPP of around 40 USD/ton. It is due to the fact that the polygeneration scheme could reduce the LCOP (levelized cost of producing 1 ton of clinker) due to the production of valorized products. It is noted that Scenario 2 is superior to other scenarios since the RenE2P cost in Scenario 2 is lower than it is in Scenario 1 and the captured CO2 rate in Scenario 2 is lower than it is in Scenario 3.