Facile Construction of Zn‐Doped Mn<sub>3</sub>O<sub>4</sub>−MnO<sub>2</sub> Vertical Nanosheets for Aqueous Zinc‐Ion Battery Cathodes
Wen‐Yin Ko, Andre Lammiduk Lubis, Ho Ya Wang, Tung Ching Wu, Shin Ting Lin, Kuan‐Jiuh Lin
Abstract
Abstract Aqueous rechargeable batteries with good electrochemical performances have been considered as compelling alternatives in miniaturized energy storage units due to their small‐size, better safety, greener manufacturing condition, and easy‐to‐recycle process. Herein, a binder‐free manganese oxide (MnO x ), comprising of MnO 2 and Mn 3 O 4 constructed by engineering it with zinc doping used as a cathode material for eco‐friendly aqueous Zn ion battery is developed. A green and simple electrochemical deposition synthesis of Zn‐doped Mn 3 O 4 −MnO 2 nanocomposite with vertically‐oriented 3D porous cereal‐like nanosheet framework (ZnMM‐NSs) is reproducibly performed directly onto the surface of AgCNT modified Ni foam in a mild aqueous ZnSO 4 +MnSO 4 electrolyte. To the best of our knowledge, this is the first report on Zn doping in Mn 3 O 4 −MnO 2 nanocomposite and the subsequent device assembly for aqueous zinc‐ion batteries. Zinc doping induced electrical/ionic conductivity enhancement, along with more active sites provided by 3D porous cereal‐like nanostructures and multiple Mn valences, this ZnMM‐NSs cell can deliver a high capacity, good rate performance, and satisfying cycling stability. Also, the Zn‐doped manganese oxides are obtained by a green method, which can reduce the entire cost, the usage of toxic solvents, the consumption of energy, and the disposable by‐product, paving the way for developing cost‐effective, easy‐to‐recycle, and environmentally friendly next‐generation energy storage systems.