Litcius/Paper detail

Visible-Light-Induced Photocatalytic Oxidative Decarboxylation of Cinnamic Acids to 1,2-Diketones

Shiv Chand, Anand Kumar Pandey, Rahul Singh, Krishna Nand Singh

2021The Journal of Organic Chemistry36 citationsDOI

Abstract

A concerted metallophotoredox catalysis has been realized for the efficient decarboxylative functionalization of α,β-unsaturated carboxylic acids with aryl iodides in the presence of perylene bisimide dye to afford 1,2-diketones.

Topics & Concepts

ChemistryDecarboxylationPerylenePhotocatalysisOxidative decarboxylationCatalysisCinnamic acidArylOxidative phosphorylationPhotochemistryOrganic chemistryVisible spectrumMoleculeOptoelectronicsPhysicsBiochemistryAlkylRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization Methods