Thermodynamic Modeling of Salting Effects in Solvent Extraction of Cobalt(II) from Chloride Media by the Basic Extractant Methyltrioctylammonium Chloride
Rayco Lommelen, Koen Binnemans
Abstract
trioctylmethylammonium chloride in toluene using the OLI mixed-solvent electrolyte (OLI-MSE) framework. This was accomplished by analyzing the water and hydrochloric acid content of the organic phase, measuring the water activity of the system, and using metal complex speciation and solvent extraction data. The full extractant concentration range cannot be modeled by the OLI-MSE framework as this framework lacks a description for reversed micelle formation. Nevertheless, salting effects and the behavior of hydrochloric acid can be accurately described with the presented extraction model, without determining specific Co(II)-salt cation interaction parameters. The resulting model shows that the salting effects originate from indirect salt cation-solvent interactions that influence the availability of water in the aqueous and organic phases.