Lanthanide-catalyzed regio- and enantioselective hydrosilylation of aryl-substituted terminal and internal alkenes
Chenhao Zhu, Yuqiao Zhou, Jia Yang, Xiaoming Feng, Shunxi Dong
Abstract
Highly regio- and enantioselective hydrosilylation of aryl-substituted terminal/internal alkenes with primary silanes was achieved using a chiral La( iii )-bisoxazoline complex.
Topics & Concepts
HydrosilylationChemistryEnantioselective synthesisArylSilanesLanthanideCatalysisOrganic chemistryAlkylSilaneIonOrganoboron and organosilicon chemistryCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions