Composite with a Glassy Nonporous Coordination Polymer Enhances Gas Adsorption Selectivity
Xin Zheng, Masaru Kato, Yohei Uemura, Daiju Matsumura, Ichizo Yagi, Kiyonori Takahashi, Shin‐ichiro Noro, Takayoshi Nakamura
Abstract
A glass-crystal composite (g-NCP/PCP), comprising a glassy nonporous coordination polymer (g-NCP) and a crystalline porous coordination polymer (PCP)/metal-organic framework, was synthesized by using a melt-quenched method. Compared to that of the PCP itself, g-NCP/PCP has an enhanced gas adsorption selectivity. The results should stimulate further studies of the chemistry of g-NCP/PCP glass-crystal composites.
Topics & Concepts
ChemistrySelectivityAdsorptionPolymerComposite numberCoordination polymerPorous mediumPorosityChemical engineeringMetal-organic frameworkPorous glassSelective adsorptionCrystal (programming language)Polymer chemistryInorganic chemistryOrganic chemistryComposite materialCatalysisMaterials scienceComputer scienceEngineeringProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMembrane Separation and Gas Transport