Control of Intermolecular Interactions toward the Production of Free-Standing Interfacial Polydopamine Films
Jakub Szewczyk, Višnja Babačić, Adam Krysztofik, Olena Ivashchenko, Mikołaj Pochylski, Robert Pietrzak, Jacek Gapiński, Bartłomiej Graczykowski, Mikhaël Bechelany, Emerson Coy
Abstract
. This modification is leading to significant enhancement of the process efficiency through moderation of the topological properties of the films, as revealed by atomic force microscopy. Next, applying infrared, Raman, and X-ray photoelectron spectroscopy, we presented small amounts of metal (B or Cu) in the final structure of PDA and simultaneously their vital role in the oxidation mechanism and cross-linking through covalent or non-covalent bonds. Therefore, we revealed the possibility of synthesizing films via the expected self-assembly mechanism which has hitherto been out of control. Moreover, modification of mechanical properties toward exceptionally elastic films through the BA-assisted synthesis pathway was shown by achieving Young's modulus value up to 24.1 ± 5.6 and 18.3 ± 6.4 GPa, using nanoindentation and Brillouin light scattering, respectively.