Reticular design and alkyne bridge engineering in donor–π–acceptor type conjugated microporous polymers for boosting photocatalytic hydrogen evolution
Mohamed Gamal Mohamed, Mohamed Hammad Elsayed, Chia‐Jung Li, Ahmed E. Hassan, Islam M. A. Mekhemer, Ahmed Fouad Musa, Mahmoud Kamal Hussien, Li–Chyong Chen, Kuei-Hsien Chen, Ho‐Hsiu Chou, Shiao‐Wei Kuo
Abstract
Through the successful application of Suzuki and Sonogashira coupling reactions, we have synthesized Py–TPA and Py–TB–TPA CMPs, demonstrating impressive hydrogen evolution rates (HER) of 3633 and 16 700 μmol g −1 h −1 , respectively.
Topics & Concepts
Conjugated microporous polymerMicroporous materialAcceptorPolymerConjugated systemMaterials scienceBridge (graph theory)Reticular connective tissueBoosting (machine learning)AlkynePhotocatalysisHydrogenPolymer chemistryPhotochemistryNanotechnologyChemistryOrganic chemistryComposite materialComputer scienceMedicinePhysicsCatalysisPathologyMachine learningCondensed matter physicsInternal medicineCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis Techniques