Naphthalenediimide-Based Hybrid Material with Eu-Substituted Polyoxometalate: Photochromism, Near-Infrared Photothermal Conversion, and C-3 Functionalization of Indoles
Silang Chen, Qi Yang, Xiang Shen, Feixiang Cheng, Jian‐Jun Liu
Abstract
Designing and developing novel photochromic materials with additional functions such as photothermal conversion and photocatalysis are challenging but meaningful objectives. Crystalline naphthalenediimide (NDI)-based hybrids are an attractive class of multifunctional materials with fast-response photoinduced electron transfer and charge separation properties. They are promising photothermal conversion materials and photocatalysts. Herein, a novel hybrid material, EuPMo 11 O 39 (L) 1.5 (H 2 O) 2 ]·DMA ( EuMo-NDI ) (L = N,N ′-di(1-oxido-4-pyridyl)-1,4,5,8-naphthalenediimide), was prepared with a solvothermal method, integrating a photoactive NDI derivative and an Eu-substituted polyoxometalate. EuMo-NDI exhibits 0D structure with sensitive photochromic behavior under UV–vis light irradiation due to fast-response photoinduced electron transfer between its components. The colored EuMo-NDI sample demonstrated efficient near-infrared photothermal conversion due to the strong absorption of the photogenerated radical anion NDI •– and mixed valence heteropoly blue in the near-infrared region. Meanwhile, EuMo-NDI is easily excited in the presence of electron donors to form the radical species, which can activate inert O 2 to superoxide radical O 2 •– . EuMo-NDI exhibited high photocatalytic activity for C-3 thiocyanation of indoles under mild conditions using white light as a driving force. This work provides an effective avenue to design novel photothermal conversion materials and photocatalysts using photochromic materials as platforms.