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Computational investigation on the photovoltaic performance of an efficient GeSe-based dual-heterojunction thin film solar cell

Jaker Hossain, Bipanko Kumar Mondal, Shaikh Khaled Mostaque

2021Semiconductor Science and Technology42 citationsDOI

Abstract

Abstract This article reports the design and computational analysis of an efficient GeSe-based n -ZnSe/ p -GeSe/ p + -WSe 2 dual-heterojunction (DH) thin film solar cell using SCAPS-1D simulation program with physical parameters from the literature. The device has been optimized considering the thickness, doping and defect density of each layer. The optimized device shows an efficiency of ∼42.18% with a short circuit current density, J SC of 47.84 mA cm −2 , an open circuit voltage, V OC of 1.07 V and fill factor, FF of 82.80%, respectively that remains within the Shockley-Queisser limit of a DH solar cell. The raised built-in potential developed between the two interfaces of the devices produces a surpassing V OC . The higher J SC is attributed to the current generated by absorption of sub-band gap photons by a tail-states-assisted two-step photon upconversion mechanism in the WSe 2 back surface field layer. These results indicate the potential of manufacturing the high efficiency GeSe-based DH solar cell in future.

Topics & Concepts

Solar cellHeterojunctionOptoelectronicsTheory of solar cellsShort circuitPhotovoltaic systemOpen-circuit voltageMaterials scienceCurrent densityBand gapThin filmDopingEnergy conversion efficiencyAbsorption (acoustics)Polymer solar cellVoltageNanotechnologyElectrical engineeringPhysicsComposite materialEngineeringQuantum mechanicsChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And PropertiesPerovskite Materials and Applications
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