Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates and <i>N</i>-substituted formamides
Wen‐Zhu Bi, Wenjie Zhang, Zi‐Jie Li, Yuanhao He, Suxiang Feng, Yang Geng, Xiaolan Chen, Lingbo Qu
Abstract
-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.
Topics & Concepts
ChemistryThiocarbamatesFormamidesPhotocatalysisMedicinal chemistryOrganic chemistryPhotochemistryFormamideCatalysisSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCatalytic C–H Functionalization Methods