A triazole-based covalent organic framework as a photocatalyst toward visible-light-driven CO<sub>2</sub> reduction to CH<sub>4</sub>
Sandip Biswas, Faruk Ahamed Rahimi, R. Kamal Saravanan, Anupam Dey, Jatin Chauhan, Devika Surendran, Sukhendu Nath, Tapas Kumar Maji
Abstract
Rational design of a TFPB-TRZ COF bearing the small and heteroatom-rich organic node TRZ (triazole moiety) which facilitates the stabilization of the CO intermediate at the imine (–CN–) site of the COF via electron donation from an N-hetero species.
Topics & Concepts
PhotocatalysisCovalent bondReduction (mathematics)Visible spectrumChemistryPhotochemistryMaterials scienceNanotechnologyOptoelectronicsOrganic chemistryCatalysisMathematicsGeometryCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesCO2 Reduction Techniques and Catalysts