Litcius/Paper detail

Poly(acrylic acid)/poly(acrylamide) hydrogel adsorbent for removing methylene blue

Qingyun Lv, Yong Shen, Yu Qiu, Min Wu, Liming Wang

2020Journal of Applied Polymer Science61 citationsDOI

Abstract

Abstract Cationic dye can cause severe damage to the environment due to their refractory degradation, complex composition and strong stability. Hydrogels as adsorbents have been widely used to treatment the wastewater with dyestuff for their low prices, simple operations, and high efficiency. This work uses poly(acrylic acid) (PAA)/poly(acrylamide)(PAM)/calcium hydroxide nanoparticles (CHN) polymeric hydrogel absorbent to eliminate methylene blue (MB) dye. First, PAM/PAA/CHN hydrogel is produced through copolymerization of acrylic acid monomer and acrylamide monomer using inorganic CHN as cross‐linker. And then, the adsorption performance of such PAM/PAA/CHN hydrogel adsorbent for adsorbing MB dye is explored at different conditions including pH, contacting time, adsorbent dosage, initial concentration of MB, and temperature. A maximum adsorption capability for adsorbing MB reaches 1,056 mg/g. Furthermore, the pseudo‐first‐order mode and Langmuir isotherm model can well describe adsorption behavior of MB dye onto such PAA/PAM/CHN hydrogel adsorbent. Thereby, as‐prepared PAA/PAM/CHN hydrogel could be a potential adsorbent for eliminating organic dyes from wastewater.

Topics & Concepts

AdsorptionAcrylic acidMethylene blueMonomerAcrylamideLangmuir adsorption modelSelf-healing hydrogelsCationic polymerizationCopolymerPolymer chemistryChemical engineeringChemistryAcid dyeMaterials scienceNuclear chemistryPolymerOrganic chemistryDyeingCatalysisEngineeringPhotocatalysisAdsorption and biosorption for pollutant removalNanomaterials for catalytic reactionsElectrochemical sensors and biosensors