Photobiocatalytic radical repositioning for enantioselective acylation of remote C–C/C–H bonds
Ming Yang, Zhouping Wu, Yuanyuan Xu, Yao Chen, Zhongqiu Xing, Xichao Peng, Jianlin Chun, Hailong Sun, Jiayu Wu, Yu Zheng, Ling Jiang, Xiaoqiang Huang
Topics & Concepts
ChemistryEnantioselective synthesisRadicalAcylationCandida antarcticaBiocatalysisPhotochemistryCombinatorial chemistryElectron transferStereochemistryKinetic resolutionAlkeneOrganic chemistryEnantiomerUnpaired electronAtom-transfer radical-polymerizationTransfer hydrogenationOrganic synthesisEnzyme catalysisPhotoredox catalysisPeptide bondSide chainSurface modificationRadical Photochemical ReactionsCyclopropane Reaction MechanismsMetalloenzymes and iron-sulfur proteins