Tuning dimensionality between 2D and 1D MOFs by lanthanide contraction and ligand-to-metal ratio
Fernando González Chávez, H.I. Beltrán
Abstract
2D/1D dimensionality tuning in LnMOFs is related to both (i) ligand-to-metal ratio and (ii) lanthanide contraction, this is only possible with Er/Tm, lighter lanthanides <italic>e.g.</italic> Pr only produced 2D MOFs, despite different ligand-to-metal ratios were used.
Topics & Concepts
LanthanideChemistryLanthanide contractionMetalCurse of dimensionalityLigand (biochemistry)Contraction (grammar)CrystallographyStereochemistryOrganic chemistryIonBiochemistryReceptorInternal medicineComputer scienceMedicineMachine learningMetal-Organic Frameworks: Synthesis and ApplicationsGa2O3 and related materials2D Materials and Applications