Pyridine-driven assembly of Zn(<scp>ii</scp>) and Cd(<scp>ii</scp>) complexes with 2-furoic acid. The role of water in a structural transformation
Daniel Ejarque, Francisco Sánchez-Férez, Núria Félez-Guerrero, Teresa Calvet, Mercè Font‐Bardía, Josefina Pons
Abstract
Coordination of the furane ring has been attempted in five Zn( ii ) and Cd( ii ) complexes and achieved by water-assisted structural transformation. It has been traced by X-ray and fluorescence experiments and a conversion pathway has been proposed.
Topics & Concepts
ChemistryTransformation (genetics)Ring (chemistry)FluorescencePyridineStereochemistryBiochemistryMedicinal chemistryOrganic chemistryPhysicsGeneQuantum mechanicsOrganometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesAsymmetric Synthesis and Catalysis