2D coordination sheets based on tetranuclear cuprofullerene pentafluorobenzoate and their electronic properties
Yuli Liu, Shun‐Ze Zhan, Guohui Zhang, Xian-Yun Tao, Kun Hu, Dengfeng Luo, Li Dang, Seik Weng Ng, Dan Li
Abstract
Two 2D coordination sheets with narrow bandgap based on tetranuclear cuprofullerene pentafluorobenzoate constructed with linear (μ 2 –η 2 :η 2 ) 2 -C 60 connecting Cu I /Cu II pentafluorobenzoate polymeric chains, were realized under solvothermal conditions.
Topics & Concepts
Materials scienceBand gapCrystallographyChemistryOptoelectronicsFullerene Chemistry and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsPorphyrin and Phthalocyanine Chemistry