Modular assembly of amines and diborons with photocatalysis enabled halogen atom transfer of organohalides for C(sp<sup>3</sup>)–C(sp<sup>3</sup>) bond formation
Rong‐Bin Liang, Tingting Miao, Xiang-Rui Li, Jia-Bo Huang, Shao‐Fei Ni, Sanliang Li, Qing‐Xiao Tong, Jian‐Ji Zhong
Abstract
B1. The strategy features operational simplicity, mild conditions and good functional group tolerance. A range of organohalides including activated alkyl chlorides, alkyl bromides (1°, 2° and 3° C-Br) as well as aromatic bromides are applicable in the strategy. Experimental and computational studies rationalize the proposed mechanism.
Topics & Concepts
HalogenPhotocatalysisDABCOChemistryHalogen bondModular designCoupling (piping)Atom (system on chip)StereochemistryPhotochemistryCrystallographyOctaneMaterials scienceOrganic chemistryCatalysisComputer scienceOperating systemEmbedded systemAlkylMetallurgyRadical Photochemical ReactionsOrganoboron and organosilicon chemistrySulfur-Based Synthesis Techniques