Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications
Saba Daliran, Ali Reza Oveisi, Chung‐Wei Kung, Ünal Şen, Amarajothi Dhakshinamoorthy, Cheng‐Hsun Chuang, Mostafa Khajeh, Mustafa Erkartal, Joseph T. Hupp
Abstract
reduction. The review underscores the importance of defect manipulation, including control over their distribution and type, to optimize the performance of Zr-MOFs. Through tailored defect engineering and precise selection of functional groups, researchers can enhance the selectivity and efficiency of Zr-MOFs for specific applications. Additionally, pore size manipulation influences the adsorption capacity and transport properties of Zr-MOFs, further expanding their potential in environmental remediation and energy conversion. Defective Zr-MOFs exhibit remarkable stability and synthetic versatility, making them suitable for diverse environmental conditions and allowing for the introduction of missing linkers, cluster defects, or post-synthetic modifications to precisely tailor their properties. Overall, this review highlights the promising prospects of defective Zr-MOFs in addressing energy and environmental challenges, positioning them as versatile tools for sustainable solutions and paving the way for advancements in various sectors toward a cleaner and more sustainable future.