Air‐Stable Violet Phosphorus/MoS<sub>2</sub> van der Waals Heterostructure for High‐Responsivity and Gate‐Tunable Photodetection
Yao Zhang, Zhu Tao, Nannan Zhang, Yubin Li, Xiaobo Li, Minglu Yan, Yue Tang, Jinying Zhang, Man Jiang, Hua Xu
Abstract
Abstract Violet phosphorus (VP), a newly emerging elemental 2D semiconductor, with attractive properties such as tunable bandgap, high carrier mobility, and unusual structural anisotropy, offers significant opportunities for designing high‐performance electronic and optoelectronic devices. However, the study on fundamental property and device application of 2D VP is seriously hindered by its inherent instability in ambient air. Here, a VP/MoS 2 van der Waals heterostructure is constructed by vertically staking few‐layer VP and MoS 2 , aiming to utilize the synergistic effect of the two materials to achieve a high‐performance 2D photodetector. The strong optical absorption of VP combining with the type‐II band alignment of VP/MoS 2 heterostructure make VP play a prominent photogating effect. As a result, the VP/MoS 2 heterostructure photodetector achieves an excellent photoresponse performances with ultrahigh responsivity of 3.82 × 10 5 A W –1 , high specific detectivity of 9.17 × 10 13 Jones, large external quantum efficiency of 8.91 × 10 7 %, and gate tunability, which are much superior to that of individual MoS 2 device or VP device. Moreover, the VP/MoS 2 heterostructure photodetector indicates superior air stability due to the effective protection of VP by MoS 2 encapsulation. This work sheds light on the future study of the fundamental property and optoelectronic device application of VP.