Litcius/Paper detail

Hydrogen storage and geo-methanation in a depleted underground hydrocarbon reservoir

Cathrine Hellerschmied, Johanna Schritter, Niels Waldmann, Artur B. Zaduryan, Lydia Rachbauer, Kerstin E. Scherr, Anitha Andiappan, Stephan Bauer, Markus Pichler, Andreas P. Loibner

2024Nature Energy112 citationsDOIOpen Access PDF

Abstract

Abstract Coupling of power-to-gas processes with underground gas storage could effectively allow surplus electricity to be stored for later use. Depleted hydrocarbon reservoirs could be used as stores, but practical experience of hydrogen storage in such sites is limited. Here we present data from a field trial that stored 119,353 m 3 of hydrogen admixed to natural gas in a depleted hydrocarbon reservoir. After 285 days, hydrogen recovery was 84.3%, indicating the process’s technical feasibility. Additionally, we report that microbes mediated hydrogen conversion to methane. In laboratory experiments studying mesocosms that mimic real reservoirs, hydrogen and carbon dioxide were converted to methane (0.26 mmol l −1 h −1 evolution rate) reproducibly over 14 cycles in 357 days. This rate theoretically allows 114,648 m 3 of methane per year to be produced in the test reservoir (equivalent to ~1.08 GWh). Our research demonstrates the efficiency of hydrogen storage and the importance of geo-methanation in depleted hydrocarbon reservoirs.

Topics & Concepts

HydrocarbonMethanationMethaneHydrogenEnvironmental scienceNatural gasCarbon dioxidePower to gasWaste managementChemistryPetroleum engineeringEnvironmental chemistryGeologyOrganic chemistryEngineeringElectrolyteElectrolysisElectrodePhysical chemistryMethane Hydrates and Related PhenomenaCO2 Sequestration and Geologic InteractionsAnaerobic Digestion and Biogas Production