Conversion of Recovered Ammonia and Carbon Dioxide into Urea in the Presence of Catalytically Active Copper Species in Nanospaces of Porous Silica Hollow Spheres
Tetsuo Umegaki, Yoshiyuki Kojima
Abstract
The present study firstly reported porous silica hollow spheres as a host material for recovery of ammonia and carbon dioxide and conversion of the compounds into urea. These compounds were effectively introduced into the hollow spheres from an aqueous solution including ammonium and carbonate ions accompanied with catalytically active copper ions from the analyses of diffuse reflectance infrared Fourier transform (DRIFT) spectra and diffusion reflectance ultraviolet-visible and near-infrared (DR UV-vis-NIR) spectra. The ammonium and carbonate ions were converted into urea in the hollow spheres at 323 K under 0.5 MPa of argon atmosphere from the results of the DRIFT spectra. From the results of nitrogen sorption isotherms and X-ray photoelectron spectra (XPS) spectra, the amount of the generated urea depended on the amount of the introduced ammonium ions and the size distribution of the nanospaces in the hollow spheres. Urea was highly generated in the hollow spheres with a high amount of ammonium ions and well-ordered nanospaces from the reactants at high density.