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In situ temperature measurements in sooting methane/air flames using synchrotron x-ray fluorescence of seeded krypton atoms

Matthew J. Montgomery, Hyunguk Kwon, Alan Kastengren, Lisa D. Pfefferle, Travis Sikes, Robert S. Tranter, Yuan Xuan, Charles S. McEnally

2022Science Advances11 citationsDOIOpen Access PDF

Abstract

Synchrotron x-ray fluorescence has been used to measure temperatures in optically dense gases where traditional methods would fail. These data provide a benchmark for stringent tests of computational fluid dynamics models for complex systems where physical and chemical processes are intimately linked. The experiments measured krypton number densities in a sooting, atmospheric pressure, nonpremixed coflow flame that is widely used in combustion research. The experiments not only form targets for the models, but the simulations also identify potential sources of uncertainties in the measurements, allowing for future improvements.

Topics & Concepts

KryptonSynchrotronSynchrotron radiationMethaneCombustionMaterials scienceCombustorIn situTemporal resolutionAtmospheric pressureAnalytical Chemistry (journal)Atomic physicsChemistryOpticsArgonPhysicsMeteorologyPhysical chemistryOrganic chemistryChromatographyAtmospheric chemistry and aerosolsAtmospheric Ozone and ClimateAtmospheric and Environmental Gas Dynamics
In situ temperature measurements in sooting methane/air flames using synchrotron x-ray fluorescence of seeded krypton atoms | Litcius