Dynamic pyridinethiol ligand shuttling within iron-anchored covalent organic frameworks boosts CO <sub>2</sub> photoreduction
Yong-Kang Zhang, Lan Zhao, Alexander O. Terent’ev, Liang‐Nian He
Abstract
A dynamic D⋯M–A structure COF can effectively suppress photogenerated charge recombination, achieving rapid electron transfer via round-trip shuttling of pyridinethiol ligands within iron-anchored COFs and thereby enhancing PCO 2 RR performance.
Topics & Concepts
Covalent bondLigand (biochemistry)ChemistryNanotechnologyMaterials scienceBiochemistryReceptorOrganic chemistryCovalent Organic Framework ApplicationsCO2 Reduction Techniques and CatalystsAdvanced Photocatalysis Techniques