Metalloradical intermediates in electrocatalytic reduction of CO<sub>2</sub> to CO: Mn <i>versus</i> Re bis-N-heterocyclic carbene pincers
Tessa H. T. Myren, Abdulaziz Alherz, Taylor A. Stinson, Chloe G. Huntzinger, Bimala Lama, Charles B. Musgrave, Oana R. Luca
Abstract
reductions mediated by group VII NHC pincer molecular electrocatalysts.
Topics & Concepts
CarbeneChemistryDelocalized electronLigand (biochemistry)Pincer movementUnpaired electronPyridinePincer ligandCatalysisCrystallographyContext (archaeology)RedoxElectrochemistryNucleophilePhotochemistryStereochemistryMedicinal chemistryInorganic chemistryPhysical chemistryMoleculeOrganic chemistryPaleontologyElectrodeBiochemistryReceptorBiologyCO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisN-Heterocyclic Carbenes in Organic and Inorganic Chemistry