Photocatalyzed decarboxylation of oxamic acids under near-infrared conditions
Ikechukwu Martin Ogbu, Dario M. Bassani, Frédéric Robert, Yannick Landais
Abstract
as catalyst is reported. The reaction was applied to the synthesis of urethanes and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes are discussed.
Topics & Concepts
DecarboxylationChemistryInfraredIrradiationOrganic chemistryMedicinal chemistryPhotochemistryCatalysisPhysicsOpticsNuclear physicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesOxidative Organic Chemistry Reactions