Improving proton conductivity of metal organic framework materials by reducing crystallinity
Huan Tang, Xueyi Lv, Juan Du, Yang Liu, Jie Liu, Lihua Guo, Xiaofeng Zheng, Hongguo Hao, Zhe Liu
Abstract
Abstract Developing a new type of proton conductive material is key to improve the energy conversion performance of proton exchange membrane fuel cell (PEMFC). In recent years, metal organic framework (MOF) matrix conductive materials have become one of the research hotspots in the field of MOF. However, the grain boundaries in MOF particles and MOF@polymer composite films make it difficult to form long‐range ordered proton transport channels. Reducing crystallinity and changing the internal structural properties of MOF matrix may effectively improve its proton conductivity. In this study, some synthesis strategies were used to induce the crystallinity of MOF matrix to improve the proton conductivity, and low‐crystallinity MOG materials were obtained. In all, eight materials were prepared. The morphology characterization and proton conductivity of MOF and MOG materials were studied to explore the influence of different crystallinities and internal structures on proton conductivity. The results explicitly indicated that for the hydrophilic materials, the proton conductivity of MOG‐MOF‐808, MOG‐UiO‐66, MOG‐HKUST‐1 was significantly improved, compared with the corresponding MOFs at 75% RH. Among them, MOG‐MOF‐808 and MOG‐UiO‐66 show strong water stability and thermal stability, ensuring that it can be applied in special and complex environments. For the hydrophobic ZIF‐8 and MOG‐ZIF‐8, both their proton conductivities are low due to the material characteristics and network structures, while the proton conductivity of MOG‐ZIF‐8 is also higher than that of ZIF‐8 at 303 K. The results show that the abundant low‐crystallinity network structure in MOG materials played a very important role in improving the proton conductivity of the hydrophilic materials.