Boosting water decomposition by sulfur vacancies for efficient CO<sub>2</sub> photoreduction
Shikang Yin, Xiaoxue Zhao, Enhui Jiang, Yan Yan, Peng Zhou, Pengwei Huo
Abstract
As the rate-determining half reaction (OER) in the overall CO 2 photoreduction, the four-electron-involving OER on S-vacancy sites was favored, therefore facilitating the hole-elimination/proton release and unleashing the CO 2 reduction half reaction.
Topics & Concepts
SulfurDecompositionPhotochemistryChemistryBoosting (machine learning)Vacancy defectDegradation (telecommunications)Materials scienceInorganic chemistryCrystallographyComputer scienceOrganic chemistryMachine learningTelecommunicationsAdvanced Photocatalysis TechniquesCO2 Reduction Techniques and CatalystsAmmonia Synthesis and Nitrogen Reduction