Boosting electrocatalytic CO<sub>2</sub>reduction reaction over viologen-functionalized metal–organic frameworks by enhancement of electron-transfer capacity
Yuliang Dong, Zi-Yan Jing, Qiu‐Jin Wu, Zi-Ao Chen, Yuan‐Biao Huang, Rong Cao
Abstract
Viologen-based MOFs were developed to show highly efficient electrocatalytic CO 2 reduction reaction with a high CO faradaic efficiency of 93.8% at 2.3 V and large CO partial current density of 111.1 mA cm −2 at 2.9 V.
Topics & Concepts
ViologenFaraday efficiencyMetal-organic frameworkElectron transferBoosting (machine learning)ElectrochemistryChemistryPhotochemistryMaterials scienceInorganic chemistryElectrodeOrganic chemistryPhysical chemistryComputer scienceMachine learningAdsorptionCO2 Reduction Techniques and CatalystsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications