Electrochemical Oxidative Arylsulfonylation and 1,<scp>2‐Alkyl</scp> Shift Sequences of Alkenyl Cyclobutanols for the Synthesis of <scp>β‐Sulfonated</scp> Cyclopentanones
Yebin Kim, Dae Young Kim
Abstract
A novel process for the synthesis of β‐sulfonated cyclopentanones via electrochemical oxidative radical arylsulfonylation and 1,2‐alkyl shift sequences of vinyl cyclobutanols was successfully developed. This approach represents a practical method for the preparation of β‐sulfonated cyclopentanones under environmentally benign reaction conditions.
Topics & Concepts
AlkylElectrochemistryChemistryOxidative phosphorylationPolymer chemistryOrganic chemistryBiochemistryElectrodePhysical chemistrySulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCatalytic C–H Functionalization Methods