Coordination microenvironment perturbed single-ion magnet behavior in a β-diketone Dy(<scp>iii</scp>) complex
Peipei Cen, Meilin Wang, Xiufang Ma, Lei Chen, Yi‐Quan Zhang, Yonghong Li, Danian Tian, Xiangyu Liu
Abstract
Employing mixed β-diketonate and bpy ligands leads to a mononuclear Dy(<sc>iii</sc>) SIM, of which the magneto-structural correlation is elucidated by the magnetic and theoretical studies, as well as a comparative study of reported analogues.
Topics & Concepts
IonCrystallographyChemistryMagnetLanthanideDysprosiumSingle-molecule magnetStereochemistryInorganic chemistryPhysicsOrganic chemistryMagnetic fieldMagnetizationQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research