Origin of intersystem crossing in highly distorted organic molecules: a case study with red light-absorbing<i>N</i>,<i>N</i>,<i>O</i>,<i>O</i>-boron-chelated Bodipys
Xue Zhang, А. А. Суханов, Xi Liu, Maria Letizia Taddei, Jianzhang Zhao, Anthony Harriman, Violeta K. Voronkova, Yan Wan, Bernhard Dick, Mariangela Di Donato
Abstract
A twisted π-conjugated framework does not necessarily promote efficacious ISC, energy matching of S 1 /T n excited states offers a more promising route to triplet enhancement.
Topics & Concepts
Intersystem crossingBoronMoleculeChemistryPhotochemistryChelationOrganic moleculesComputational chemistryInorganic chemistryPhysicsAtomic physicsOrganic chemistryExcited stateSinglet stateLuminescence and Fluorescent MaterialsMolecular Sensors and Ion DetectionOrganic Light-Emitting Diodes Research