Spatially programmed regioisomeric conjugated microporous polymers modulating zinc sites for selective CO<sub>2</sub> photoreduction to CH<sub>4</sub>
Xingwang Lan, Juan Wang, Chen Lü, Haobo Xu, Tianjun Zhang, Yong Chen
Abstract
A topological spatial engineering strategy was proposed to precisely regulate dipole polarization and active sites in conjugated microporous polymers, achieving high photocatalytic CO 2 -to-CH 4 conversion activity and selectivity.
Topics & Concepts
Conjugated microporous polymerMicroporous materialConjugated systemSelectivityPhotocatalysisPolymerZincCatalysisChemistryCombinatorial chemistryPhotochemistryOrganic chemistryCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications