Accelerated reactions of amines with carbon dioxide driven by superacid at the microdroplet interface
Kai‐Hung Huang, Zhenwei Wei, R. Graham Cooks
Abstract
followed by nucleophilic attack by the amine is analogous to that previously advanced for imidazole formation from carboxylic acids and diamines.
Topics & Concepts
Carbamic acidChemistryNucleophileDeprotonationProtonationCarbon dioxideAmine gas treatingOrganic chemistryPhotochemistryReagentDimethylamineNucleophilic additionReaction mechanismSuperacidInorganic chemistryCatalysisIonCO2 Reduction Techniques and CatalystsIonic liquids properties and applicationsCarbon Dioxide Capture Technologies