Microwave-assisted one-pot preparation of magnetic cactus-derived hydrochar for efficient removal of lead(Ⅱ) and phenol from water: Performance and mechanism exploration
Jianhua Qu, Zhaolin Du, Yue Lei, Man Li, Wei Peng, Mengning Wang, Jie Liu, Qi Hu, Lei Wang, Yifan Wang, Ying Zhang
Abstract
A novel magnetic hydrochar derived from cactus cladode (MW-MHC) was successfully synthesized through one-pot microwave-assisted process for efficiently removing lead(Pb)(Ⅱ) and phenol. From batch adsorption experiments, MW-MHC possessed the highest uptake amounts for Pb(Ⅱ) and phenol of 139.34 and 175.32 mg/g within 20 and 60 min, respectively. Moreover, the removal of Pb(Ⅱ) and phenol by MW-MHC remained essentially stable under the interference of different co-existing cations, presenting the excellent adaptability of MW-MHC. After three cycles of regeneration experiments, MW-MHC still had preferable adsorption performance and could be easily recycled, indicating its excellent reusability. Significantly, the uptake mechanisms of Pb(Ⅱ) on MW-MHC were regarded as chemical complexation, pore filling, precipitation, and electrostatic attraction. Meanwhile, the phenol uptake might be dominated by π-π interaction and hydrogen bonding. The above consequences revealed that MW-MHC with high removal performance was a promising adsorbent for remediating wastewater containing heavy metals and organics.