Synthesis of [60]fullerene-fused dihydrobenzooxazepines<i>via</i>the palladium-catalyzed oxime-directed C–H bond activation and subsequent electrochemical functionalization
Chen Wang, Zhan Liu, Zheng‐Chun Yin, Guan‐Wu Wang
Abstract
The palladium-catalyzed heteroannulation of [60]fullerene with oximes affords the unprecedented seven-membered [60]fullerene-fused dihydrobenzooxazepines, which can be further derivatized electrochemically.
Topics & Concepts
ChemistryPalladiumFullereneOximeSurface modificationCatalysisElectrochemistryCombinatorial chemistryOrganic chemistryElectrodePhysical chemistryFullerene Chemistry and ApplicationsCatalytic C–H Functionalization MethodsSynthesis and Properties of Aromatic Compounds