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Structural Insights into Microbial One-Carbon Metabolic Enzymes Ni–Fe–S-Dependent Carbon Monoxide Dehydrogenases and Acetyl-CoA Synthases

Alison Biester, Andrea N. Marcano-Delgado, Catherine L. Drennan

2022Biochemistry26 citationsDOIOpen Access PDF

Abstract

and methane production. Here we review some of the recent advances in understanding the structure and mechanism of CODHs, CODH/ACSs, and ACDSs, their unusual metallocofactors, and their unique metabolic roles in the human gut and elsewhere.

Topics & Concepts

Carbon monoxide dehydrogenaseAcetyl-CoAChemistryCarbon monoxideEnzymeBiochemistryCarbon fibersCarbon fixationAcetogenesisCatalysisStereochemistryOrganic chemistryMethaneMethanogenesisMaterials sciencePhotosynthesisComposite numberComposite materialPorphyrin Metabolism and DisordersMetalloenzymes and iron-sulfur proteinsAnaerobic Digestion and Biogas Production