Photocatalytic redox-neutral selective single C(sp<sup>3</sup>)–F bond activation of perfluoroalkyl iminosulfides with alkenes and water
Tao Wang, Yuan-Yuan Zong, Tao Huang, Xiaoling Jin, Li‐Zhu Wu, Qiang Liu
Abstract
Site-selective and direct C–F bond functionalization of polyfluorinated iminosulfides was achieved to synthesize 3-fluoro-3-perfluoroalkyl-γ-lactams under photoredox-neutral conditions.
Topics & Concepts
PhotocatalysisRedoxChemistryPhotochemistryInorganic chemistryCatalysisOrganic chemistryFluorine in Organic ChemistrySulfur-Based Synthesis TechniquesRadical Photochemical Reactions