Reduction of Capacity Fading in High-Voltage NMC Batteries with the Addition of Reduced Graphene Oxide
Yahya M. Alqahtani, Quinton L. Williams
Abstract
Lithium-ion batteries for electric vehicles (EV) require high energy capacity, reduced weight, extended lifetime and low cost. EV manufacturers are focused on Ni-rich layered oxides because of their promising attributes, which include the ability to operate at a relatively high voltage. However, these cathodes, usually made with nickel-manganese-cobalt (NMC811), typically experience accelerated capacity fading when operating at a high voltage. In this research, reduced graphene oxide (rGO) is added to a NMC811 cathode material to improve the performance in cyclability studies. Batteries made with rGO/NMC811 cathodes showed a 17% improvement in capacity retention after 100 cycles of testing over a high-voltage operating window of 2.5-4.5 V.