Litcius/Paper detail

Ultrahigh Sensitive Trace Gas Sensing System with Dual Fiber-Optic Cantilever Multiplexing-Based Differential Photoacoustic Detection

Xinyu Zhao, Zhengzhi Wang, Chenxi Li, Heng Wang, Hongchao Qi, Min Guo, Fengxiang Ma, Ke Chen

2024Analytical Chemistry48 citationsDOI

Abstract

An ultrahigh sensitive trace gas sensing system was presented with dual cantilever-based differential photoacoustic detection. By combining the double enhancement of multipass absorption and optical differential detection, the gas detection sensitivity was significantly improved. The dual-channel synchronous photoacoustic detection was realized by fiber-optic Fabry–Perot interference spectrum multiplexing. The photoacoustic signals detected by two fiber-optic cantilever microphones installed in a differential photoacoustic cell (DPAC) were out of phase, while the detected gas flow noises were in phase. The optical differential detection method achieved both highly sensitive optical interference measurement and differential noise suppression. In the multipass configuration, the interaction path between excitation light and target gas achieved 4.1 m, which improved the photoacoustic signal by an order of magnitude compared with a single reflection. The maximum gas flow allowed by the system based on the DPAC was 250 sccm, which realized the dynamic monitoring of H 2 S in the SF 6 background. The detection limit for H 2 S in SF 6 background was 5.1 ppb, which corresponds to the normalized noise equivalent absorption coefficient of 9 × 10 –10 cm –1 W Hz –1/2 .

Topics & Concepts

Trace gasChemistryOpticsOptical fiberCantileverPhotoacoustic spectroscopyMultiplexingInterference (communication)Noise (video)Fiber optic sensorSensitivity (control systems)Channel (broadcasting)Materials sciencePhotoacoustic imaging in biomedicinePhysicsElectronic engineeringComputer scienceElectrical engineeringEngineeringArtificial intelligenceComposite materialOrganic chemistryImage (mathematics)Spectroscopy and Laser ApplicationsAdvanced Chemical Sensor TechnologiesGas Sensing Nanomaterials and Sensors
Ultrahigh Sensitive Trace Gas Sensing System with Dual Fiber-Optic Cantilever Multiplexing-Based Differential Photoacoustic Detection | Litcius