One- and Two-Dimensional Iodine-Rich Iodobismuthate(III) Complexes: Structure, Optical Properties, and Features of Halogen Bonding in the Solid State
Sergey A. Adonin, Andrey N. Usoltsev, Alexander S. Novikov, Boris A. Kolesov, Vladimir P. Fedin, Maxim N. Sokolov⧫
Abstract
), where the halometalate anions are connected by diiodine linkers into one- or two-dimensional supramolecular structures. Both complexes reveal narrow optical band gaps and fairly high thermal stability, favoring their potential use in photovoltaic devices.
Topics & Concepts
ChemistryHalogenIodideIodineSupramolecular chemistrySolid-stateCrystallographyHalogen bondThermal stabilityBand gapIodine compoundsInorganic chemistryCrystal structurePhysical chemistryOrganic chemistryAlkylOptoelectronicsPhysicsPerovskite Materials and ApplicationsCrystallography and molecular interactionsOrganic and Molecular Conductors Research